Here and Now, on NBC
IMDb; Sitcoms Online; TV Tango; Wikipedia

Mainly what I remember about this is that it starred Malcolm-Jamal Warner (of The Cosby Show fame) as Alexander "A.J." James. Also I remember its theme song was "Tennessee" by Arrested Development, which seemed odd, given that the show wasn't set in Tennessee. Anyway, Warner played a psych major in post-grad school, who became a counselor at a youth center in Harlem. I also vaguely recall Daryl "Chill" Mitchell (who I would shortly thereafter see in The John Larroquette Show) playing T, who worked at the youth center. And I vaguely recall A.J. had a potential love interest in Danielle (played by Rachael Crawford, who I knew from E.N.G.). I'm sure there were other characters, including kids who attended the youth center. But I really don't remember any of the other characters much at all. And even the ones I've mentioned, I couldn't have told you their names without looking online. It was probably a decent show, so it's a shame I don't remember it better.